Battery Cell and Battery Module Including the Same

ABSTRACT

Disclosed is a battery cell, which includes a battery case having an accommodation portion in which an electrode assembly is mounted, and a sealing portion formed by sealing an outer periphery thereof by heat fusion; an electrode lead electrically connected to an electrode tab included in the electrode assembly and protruding out of the battery case via the sealing portion; and a lead film located at a portion corresponding to the sealing portion in at least one of an upper portion and a lower portion of the electrode lead, wherein the lead film has a dented portion formed at an inside thereof, and the dented portion extends via the sealing portion and is closed inside the lead film.

TECHNICAL FIELD

The present application claims priority to Korean Patent Application No.10-2021-0003185 filed on Jan. 11, 2021 in the Republic of Korea.

The present disclosure relates to a battery cell and a battery moduleincluding the same, and more particularly, to a battery cell withimproved external emission of gas generated inside the battery cell, anda battery module including the same.

BACKGROUND ART

As technology development and demand for mobile devices increase, thedemand for secondary batteries as an energy source is rapidlyincreasing. In particular, secondary batteries are of great interest asenergy sources not only for mobile devices such as mobile phones,digital cameras, notebooks and wearable devices, but also for powerdevices such as electric bicycles, electric vehicles and hybrid electricvehicles.

Depending on the shape of a battery case, these secondary batteries areclassified into a cylindrical battery and a prismatic battery in which abattery assembly is included in a cylindrical or prismatic metal can,and a pouch-type battery in which the battery assembly is included in apouch-type case of an aluminum laminate sheet. Here, the batteryassembly included in the battery case is a power element including apositive electrode, a negative electrode, and a separator interposedbetween the positive electrode and the negative electrode, and capableof charging and discharging, and is classified into a jelly-roll type inwhich long sheet-type positive and negative electrodes coated with anactive material are wound with a separator being interposedtherebetween, and a stack type in which a plurality of positive andnegative electrodes are sequentially stacked with a separator beinginterposed therebetween.

Among them, in particular, a pouch-type battery in which a stack-type orstack/folding-type battery assembly is included in a pouch-type batterycase made of an aluminum laminate sheet is being used more and more dueto low manufacturing cost, small weight, and easy modification.

FIG. 1 is a top view showing a conventional battery cell. FIG. 2 is across-sectional view, taken along the axis a-a′ of FIG. 1 . Referring toFIGS. 1 and 2 , a conventional battery cell 10 includes a battery case20 having an accommodation portion 21 in which a battery assembly 11 ismounted, and a sealing portion 25 formed by sealing an outer peripherythereof by heat fusion. Here, the battery cell 10 includes an electrodelead 30 protruding out of the battery case 20 via the sealing portion25, and a lead film 40 is located between upper and lower portions ofthe electrode lead 30 and the sealing portion 25.

However, as the energy density of the battery cell increases in recentyears, there is a problem that the amount of gas generated inside thebattery cell also increases. In the case of the conventional batterycell 10, a component capable of discharging the gas generated inside thebattery cell is not included, so a venting may occur in the battery celldue to gas generation. In addition, moisture may penetrate into thebattery cell damaged by the venting, which may cause side reactions, andthere is a problem that battery performance deteriorates and additionalgas is generated. Accordingly, there is an increasing need to develop abattery cell with improved external emission of gas generated inside thebattery cell.

DISCLOSURE Technical Problem

The present disclosure is designed to solve the problems of the relatedart, and therefore the present disclosure is directed to providing abattery cell with improved external emission of gas generated inside thebattery cell, and a battery module including the same.

The object to be solved by the present disclosure is not limited to theabove-mentioned object, and the objects not mentioned here may beclearly understood by those skilled in the art from this specificationand the accompanying drawings.

Technical Solution

In one aspect of the present disclosure, there is provided a batterycell, comprising: a battery case having an accommodation portion inwhich an electrode assembly is mounted, and a sealing portion formed bysealing an outer periphery thereof by heat fusion; an electrode leadelectrically connected to an electrode tab included in the electrodeassembly and protruding out of the battery case via the sealing portion;and a lead film located at a portion corresponding to the sealingportion in at least one of an upper portion and a lower portion of theelectrode lead, wherein the lead film has a dented portion formed at aninside thereof, and the dented portion extends via the sealing portionand is closed inside the lead film.

The battery cell may further comprise an inner layer configured to coverat least one surface of inner surfaces of the dented portion of the leadfilm.

A material of the inner layer may have a higher melting point comparedto a material of the lead film and may not react with an electrolyticsolution.

The lead film may contain a polyolefin-based material.

The inner layer may contain at least one of polyolefin-based materials,fluorine-based materials and porous ceramic-based materials.

The lead film may have a length greater than a width of the electrodelead.

The dented portion may be located over the electrode lead.

The dented portion may be located between an end of the electrode leadand an end of the lead film.

The lead film may have a width greater than a width of the sealingportion and smaller than a length of the electrode lead.

Both ends of the dented portion may be located between an end of thesealing portion and an end of the lead film, respectively.

The dented portion may have a rectangular shape.

The dented portion may include a pair of first dented portions and apair of second dented portions connected to each other, the first dentedportion may extend along a protruding direction of the electrode lead,and the second dented portion may extend along a longitudinal directionof the sealing portion.

The lead film may include a first lead film and a second lead film, thefirst lead film may be located at an upper portion of the electrodelead, and the second lead film may be located at a lower portion of theelectrode lead.

The electrode lead may be located between the first lead film and thesecond lead film, and the first lead film and the second lead film maybe connected to each other.

The dented portion may be located in at least one of the first lead filmand the second lead film.

The other end of the dented portion may be located outer than an outersurface of the battery case.

One end of the dented portion may be located inner than an inner surfaceof the battery case.

An area in which the dented portion is located outer than the outersurface of the battery case may be the same as an area in which thedented portion is located inner than an inner surface of the batterycase.

An area in which the dented portion is located outer than the outersurface of the battery case may be greater than an area in which thedented portion is located inner than an inner surface of the batterycase.

Based on a protruding direction of the electrode lead, a width of thelead film surrounding a front surface of the dented portion may be 2 mmor more.

A thickness of the lead film surrounding an upper surface of the dentedportion may be 100 μm to 300 μm.

The lead film may have gas permeability of 20 Barrer to 60 Barrer at 60°C.

The lead film may have a moisture penetration amount of 0.02 g to 0.2 gfor 10 years at 25° C., 50% RH.

In another aspect of the present disclosure, there is also provided abattery module, comprising the battery cell described above.

Advantageous Effects

According to the embodiments, the present disclosure provides a batterycell having a dented portion inside a lead, and a battery moduleincluding the same, so it is possible to improve the external emissionof gas generated inside the battery cell.

The effect of the present disclosure is not limited to the aboveeffects, and the effects not mentioned here will be clearly understoodby those skilled in the art from this specification and the accompanyingdrawings.

DESCRIPTION OF DRAWINGS

FIG. 1 is a top view showing a conventional battery cell.

FIG. 2 is a cross-sectional view, taken along the axis a-a′ of FIG. 1 .

FIG. 3 is a top view showing a battery cell according to thisembodiment.

FIG. 4 is a perspective view showing an electrode lead included in thebattery cell of FIG. 3 .

FIG. 5 is a cross-sectional view, taken along the axis c-c′ of FIG. 4 .

FIG. 6 is a cross-sectional view, taken along the axis d-d′ of FIG. 4 .

FIG. 7 is a cross-sectional view, taken along the axis b-b′ of FIG. 3 .

FIG. 8 is a diagram showing the flow of gas generated inside the batterycell and discharged to the outside.

FIG. 9 is an enlarged view showing the electrode lead in the batterycell of FIG. 3 .

FIG. 10 is a diagram showing an electrode lead according to anotherembodiment of FIG. 9 .

FIG. 11 is an enlarged view showing the electrode lead according to alocation of the sealing portion in (a) of FIG. 9 .

BEST MODE

Hereinafter, with reference to the accompanying drawings, variousembodiments of the present disclosure will be described in detail so asto be easily implemented by those skilled in the art. The presentdisclosure may be implemented in various different forms and is notlimited to the embodiments described herein.

In order to clearly explain the present disclosure, parts irrelevant tothe description are omitted, and identical or similar components areendowed with the same reference signs throughout the specification.

In addition, since the size and thickness of each component shown in thedrawings are arbitrarily expressed for convenience of description, thepresent disclosure is not necessarily limited to the drawings. In orderto clearly express various layers and regions in the drawings, thethicknesses are enlarged. Also, in the drawings, for convenience ofexplanation, the thickness of some layers and regions is exaggerated.

In addition, throughout the specification, when a part “includes” acertain component, it means that other components may be furtherincluded, rather than excluding other components, unless otherwisestated.

In addition, throughout the specification, when referring to “top view”,it means that the target part is viewed from above, and when referringto “cross-sectional view”, it means that a vertically-cut section of thetarget part is viewed from a side.

Hereinafter, a pouch battery cell 100 according to an embodiment of thepresent disclosure will be described. However, here, the descriptionwill be made based on one side surface of both side surfaces of thepouch battery cell 100, but it is not necessarily limited thereto, andthe same or similar contents may be described in the case of the otherside surface.

FIG. 3 is a top view showing a battery cell according to thisembodiment.

Referring to FIG. 3 , the battery cell 100 according to this embodimentincludes a battery case 200, an electrode lead 300, and a lead film 400.

The battery case 200 includes an accommodation portion 210 in which anelectrode assembly 110 is mounted, and a sealing portion 250 formed bysealing an outer periphery thereof by heat fusion. The battery case 200may be a laminate sheet including a resin layer and a metal layer. Morespecifically, the battery case 200 may be made of a laminate sheet, andmay include an outer resin layer forming the outermost layer, a barriermetal layer preventing penetration of materials, and an inner resinlayer for sealing.

Also, the electrode assembly 110 may have a structure of a jelly-rolltype (winding type), a stack type (lamination type), or a composite type(stack/folding type). More specifically, the electrode assembly 110 mayinclude a positive electrode, a negative electrode, and a separatordisposed therebetween.

Hereinafter, the electrode lead 300 and the lead film 400 will be mainlydescribed.

FIG. 4 is a perspective view showing an electrode lead included in thebattery cell of FIG. 3 .

Referring to FIGS. 3 and 4 , the electrode lead 300 is electricallyconnected to an electrode tab (not shown) included in the electrodeassembly 110, and protrudes out of the battery case 200 via the sealingportion 250. In addition, the lead film 400 is located at a portioncorresponding to the sealing portion 250 in at least one of an upperportion and a lower portion of the electrode lead 300. Accordingly, thelead film 400 may improve the sealing properties of the sealing portion250 and the electrode lead 300 while preventing a short circuit fromoccurring in the electrode lead 300 during thermal fusion.

FIG. 5 is a cross-sectional view, taken along the axis c-c′ of FIG. 4 .FIG. 6 is a cross-sectional view, taken along the axis d-d′ of FIG. 4 .

Referring to FIGS. 5 and 6 , in the lead film 400, a dented portion 450is formed inside the lead film 400, and the dented portion 450 extendsvia the sealing portion 250 but is closed in the lead film 400.

Accordingly, in the lead film 400, the gas generated inside the batterycase 200 may be discharged to the dented portion 450 due to the pressuredifference with the inside of the dented portion 450, and the gasintroduced into the dented portion 450 may be discharged toward theoutside due to the pressure difference. In addition, since the dentedportion 450 of the lead film 400 is closed, the dented portion 450 maynot be exposed to the electrolytic solution inside the battery case 200,and the airtightness and durability of the pouch may be secured.

By adjusting the area where the dented portion 450 is exposed in each ofthe inner and outer sides of the battery case 200, the amount ofdischarged gas may be controlled.

FIG. 7 is a cross-sectional view, taken along the axis b-b′ of FIG. 3 .

Referring to FIG. 7 , one end of the dented portion 450 may be locatedinner than the inner surface of the battery case 200. In addition, theother end of the dented portion 450 may be located outer than the outersurface of the battery case 200.

Here, the inner surface of the battery case 200 means an end of thesealing portion 250 of the battery case 200 at the inner side of thebattery. In addition, the outer surface of the battery case 200 means anend of the sealing portion 250 of the battery case 200 at the outer sideof the battery.

Accordingly, the lead film 400 may maximize the area of the dentedportion 450 and discharge a large amount of gas.

In one embodiment of the present disclosure, the area in which thedented portion 450 is located outer than the outer surface of thebattery case 200 may be the same as the area in which the dented portion450 is located inner than the inner surface of the battery case 200.

In another embodiment of the present disclosure, the area in which thedented portion 450 is located outer than the outer surface of thebattery case 200 may be larger than the area in which the dented portion450 is located inner than the inner surface of the battery case 200. Theamount of discharged gas is proportional to the product of the gasdischarge area and the pressure. Since the pressure inside the batterycase 200 is greater than the pressure outside the battery case 200, ifthe area in which the dented portion 450 is located outer than the outersurface of the battery case 200 is larger than the area in which thedented portion 450 is located inner than the inner surface of thebattery case 200, the gas generated inside the battery case 200 may bemore easily discharged to the outside.

In one embodiment of the present disclosure, the area in which thedented portion 450 is located outer than the outer surface of thebattery case 200 may be 40 mm² to 80 mm². This is a size in which about0.5 cc to 3 cc of gas can be discharged per day based on an internalpressure of 1 atm at 60° C. In addition, this is a size in which themoisture penetration amount may be 0.02 g to 0.2 g for 10 years at 25°C., 50% RH.

Referring to FIG. 7 , the thickness H of the lead film 400 surroundingthe upper and/or lower surfaces of the dented portion 450 may be 100 μmto 300 μm, or 100 μm to 200 μm. If the thickness H of the lead film 400surrounding the upper surface of the dented portion 450 satisfies theabove range, the gas inside the battery case 200 may be more easilydischarged to the outside.

Referring to FIG. 7 , based on the protruding direction of the electrodelead 300, the width W of the lead film 400 surrounding the front and/orrear surfaces of the dented portion 450 may be 2 mm or more, or 2 mm to3 mm. Here, the width of the lead film 400 surrounding the front surfaceof the dented portion 450 means a maximum value of the distance betweenthe outer end of the battery case 200 at the dented portion 450 and theouter end of the battery case 200 at the lead film 400, and the width ofthe lead film 400 surrounding the rear surface of the dented portion 450means a maximum value of the distance between the inner end of thebattery case 200 at the dented portion 450 and the inner end of thebattery case 200 at the lead film 400. If the width W of the lead film400 surrounding the front and/or rear surface of the dented portion 450satisfies the above range, the phenomenon that the lead film 400 is tornwhile the gas generated inside the battery case 200 is discharged to theoutside may be easily prevented.

FIG. 8 is a diagram showing the flow of gas generated inside the batterycell and discharged to the outside.

Referring to FIG. 8 , the gas generated inside the battery cell 100 maybe discharged toward the dented portion 450 of the lead film 400. Here,the internal pressure of the battery cell 100 is higher than theinternal pressure of the dented portion 450, and the resulting pressuredifference may act as a driving force of the gas. In addition, theinside of the dented portion 450 may have a pressure difference from theoutside due to the gas introduced from the inside of the battery cell100, so that the gas introduced into the dented portion 450 may bedischarged to the outside.

Accordingly, the gas generated inside the battery cell 100 may bedischarged toward the dented portion 450, and the gas introduced intothe dented portion 450 may be easily discharged toward the outside. Inaddition, the amount of gas generated inside the battery cell 100 anddischarged to the outside may also be increased.

At this time, the gas generated inside the battery case 200 may bedischarged along the Z-axis direction via the dented portion 450 and thelead film 400 surrounding the upper surface of the dented portion. Forexample, when the dented portion 450 is exposed to the outside of thebattery case 200, the gas generated inside the battery case 200 may bedischarged along the Z-axis direction via the dented portion 450 and thelead film 400 surrounding the upper surface of the dented portion.

In one embodiment of the present disclosure, the gas permeability of thelead film 400 may be 20 Barrer to 60 Barrer, or 30 Barrer to 40 Barrerat 60° C. For example, the carbon dioxide permeability of the lead film400 may satisfy the above range. In addition, the gas permeability maysatisfy the above range at 60° C. based on the thickness of the leadfilm 400 of 200 μm. If the gas permeability of the lead film 400satisfies the above range, the gas generated inside the secondarybattery may be more effectively discharged.

In this specification, the gas permeability may be measured by ASTMF2476-20.

In one embodiment of the present disclosure, the moisture penetrationamount of the lead film 400 may be 0.02 g to 0.2 g, or 0.02 g to 0.04 g,or 0.06 g, or 0.15 g for 10 years at 25° C., 50% RH. If the moisturepenetration amount of the lead film 400 satisfies the above range, thepenetration of moisture from the lead film 400 may be more effectivelyprevented.

In one embodiment of the present disclosure, the lead film 400 may havea gas permeability of 20 Barrer to 60 Barrer at 60° C. and a moisturepenetration amount of 0.02 g to 0.2 g at 25° C., 50% RH for 10 years. Ifthe gas permeability and the moisture penetration amount of the leadfilm 400 satisfy the above ranges, the penetration of moisture from theoutside may be more effectively prevented while discharging the gasgenerated inside the secondary battery.

The moisture penetration amount of the lead film 400 may be measured byadopting the ASTM F 1249 method. At this time, the moisture penetrationamount may be measured using equipment officially certified by MCOON.

In one embodiment of the present disclosure, the lead film 400 mayinclude a polyolefin-based resin. For example, the lead film 400 mayinclude a polyolefin-based resin satisfying the gas permeability and/ormoisture penetration amount values described above. The polyolefin-basedresin may include at least one material selected from the groupconsisting of polypropylene, polyethylene, and polyvinyl difluoride(PVDF). While the lead film 400 contains polypropylene, the gaspermeability of the lead film 400 may be 20 Barrer to 60 Barrer at 60°C. Also, the moisture penetration amount may be 0.06 g to 0.15 g. Inthis case, the gas generated inside the secondary battery may be moreeffectively discharged, and the penetration of moisture from the outsidemay be easily prevented.

In addition, since the lead film 400 is made of the above-describedmaterial, the lead film 400 may maintain the airtightness of the batterycell 100 and prevent leakage of the internal electrolytic solution.

In addition, referring to FIGS. 5 and 6 , the lead film 400 may furtherinclude an inner layer 410 covering at least one of the inner surfacesof the dented portion 450.

For example, referring to FIGS. 5(a) and 6(a), the inner layer 410 inthe dented portion 450 may cover the entire surface of the lead film400. That is, the inner layer 410 may be formed on the entire innersurface of the dented portion 450.

Accordingly, even if the lead film 400 is heat-fused together with thesealing portion 250 in a state of being located in at least one of theupper and lower portions of the electrode lead 300, the dented portion450 may be preserved in a non-heat-fused state by the inner layer 410.

As another example, referring to FIGS. 5(b) and 6(b), the inner layer410 may cover an upper surface or a lower surface among the innersurfaces of the dented portion 450. That is, the dented portion 450 mayhave an inner layer 410 formed on at least one of the upper and lowersurfaces facing each other.

Accordingly, while the lead film 400 minimizes the inner layer 410formed in the dented portion 450, the dented portion 450 may bepreserved in a non-heat-fused state by the inner layer 410. In addition,the manufacturing process may be simplified and the cost may be reduced.

More specifically, the inner layer 410 may be made of a material havinga higher melting point compared to the material constituting the leadfilm 400. In addition, the inner layer 410 may be made of a materialthat does not react with the electrolytic solution contained in thebattery case 200. Accordingly, since the inner layer 410 is made of theabove-described material, the inner layer 410 does not separately reactwith the electrolytic solution and does not cause heat fusion, thermaldeformation, or the like in the high-temperature heat fusion process, sothat the dented portion 450 may be kept blank. In addition, the gasgenerated in the battery case 200 may be easily discharged to theoutside.

In one embodiment of the present disclosure, the thickness of the innerlayer 410 may be 100 μm or less.

In one embodiment of the present disclosure, the gas permeability of theinner layer 410 may be 40 Barrer or more. For example, the carbondioxide permeability of the inner layer 410 may satisfy the above range.

For example, the inner layer 410 may include at least one ofpolyolefin-based materials, fluorine-based materials, and porousceramic-based materials. For example, the inner layer 410 may include atleast one of polyolefin-based materials, fluorine-based materials, andporous ceramic-based materials that satisfies the above gas permeabilityvalue. The polyolefin-based material may include at least one materialselected from the group consisting of polypropylene, polyethylene, andpolyvinyl difluoride (PVDF). The fluorine-based material may include atleast one material selected from the group consisting ofpolytetrafluoroethylene and polyvinylidene fluoride. In addition, theinner layer 410 may include a getter material, so that gas permeabilitymay be increased while water permeability may be minimized. As anexample, the getter material may be calcium oxide (CaO), barium oxide(BaO), lithium chloride (LiCl), silica (SiO₂), or the like, and anymaterial reacting with water (H₂O) can be used without being limitedthereto.

The inner layer 410 may have an adhesive material between the lead film400 and the inner layer 410 or may be extruded together with the leadfilm 400 and adhered to the lead film 400. The adhesive material mayinclude an acryl-based material. In particular, when the inner layer 410is extruded together with the lead film 400, the gas permeability of theinner layer 410 may be 40 Barrer or more.

FIG. 9 is an enlarged view showing the electrode lead in the batterycell of FIG. 3 . FIG. 10 is a diagram showing an electrode leadaccording to another embodiment of FIG. 9 . FIG. 11 is an enlarged viewshowing the electrode lead according to a location of the sealingportion in (a) of FIG. 9 .

Referring to FIGS. 9 and 10 , in the lead film 400, the dented portion450 may be formed at various positions with respect to the electrodelead 300.

For example, as shown in FIGS. 9(a) and 10(a), in the lead film 400, thedented portion 450 may be located over the electrode lead 300. Morespecifically, the dented portion 450 may be formed at a positioncorresponding to the center of the electrode lead 300.

As another example, as shown in FIGS. 9(b) and 10(b), the length of thelead film 400 may be greater than the width of the electrode lead 300,and the dented portion 450 may be located between the end of theelectrode lead 300 and the end of the lead film 400. Here, the length ofthe lead film 400 means a maximum value of the distance between one endand the other end of the lead film 400 in a direction orthogonal to theprotruding direction of the electrode lead 300, and the width of theelectrode lead 300 means a maximum value of the distance between one endand the other end of the electrode lead 300 in a direction orthogonal tothe protruding direction of the electrode lead 300. In other words, inthe lead film 400, the dented portion 450 may be formed at a positionavoiding the electrode lead 300. However, the position of the dentedportion 450 is not limited to the above, and the dented portion 450 maybe formed at an appropriate position within the lead film 400.

Accordingly, by adjusting the position of the dented portion 450 formedin the lead film 400, the durability and airtightness of the lead film400 may be controlled. In addition, if necessary, by adjusting the sizeof the dented portion 450 according to the position of the dentedportion 450, it is possible to simplify the manufacturing process andreduce the cost.

Referring to FIGS. 9 and 10 , in the lead film 400, the dented portion450 may be formed in various shapes.

For example, as shown in FIG. 9 , the dented portion 450 may include apair of first dented portions and a pair of second dented portionsconnected to each other, where the first dented portion may extend alongthe protruding direction of the electrode lead 300 and the second dentedportion may extend along the longitudinal direction of the sealingportion 250. Here, the longitudinal direction of the sealing portion 250refers to a direction perpendicular to the protruding direction of theelectrode lead 300.

As another example, the dented portion 450 may have a rectangular shapeas shown in FIG. 10 . Here, the width of the lead film 400 may begreater than the width of the sealing portion 250 and may be smallerthan the length of the electrode lead 300. Here, the width of the leadfilm 400 means a maximum value of the distance between one end and theother end of the lead film in the protruding direction of the electrodelead 300. The width of the sealing portion 250 means a maximum value ofthe distance between one end and the other end of the sealing portion250 in the protruding direction of the electrode lead 300. The length ofthe electrode lead 300 means a maximum value of the distance between oneend and the other end of the electrode lead 300 in the protrudingdirection of the electrode lead 300. At this time, both ends of thedented portion 450 may be located between the end of the sealing portion250 and the end of the lead film 400, respectively. However, the shapeof the dented portion 450 is not limited to the above, and the dentedportion 450 may be formed in an appropriate shape within the lead film400.

Accordingly, by adjusting the shape of the dented portion 450 formed inthe lead film 400, the durability and airtightness of the lead film 400may be controlled. In addition, by changing the shape of the dentedportion 450 as necessary, it is possible to simplify the manufacturingprocess and reduce cost.

Referring to FIG. 11 , in the lead film 400, one surface of the dentedportion 450 adjacent to the outside may be formed adjacent to the end ofthe lead film 400. Comparing FIGS. 11(a) and 11(b), even if the positionof the sealing portion 250 in contact with the lead film 400 is changed,it may be found that there is no influence on one surface of the dentedportion 450 adjacent to the outside. Here, although FIG. 11 relates tothe dented portion 450 having the shape of FIG. 9 , the same descriptionmay be applied to the case of FIG. 10 .

Accordingly, in this embodiment, within the error range according to thepositions of the lead film 400 and the sealing portion 250 generatedduring the heat fusion process, the one surface of the dented portion450 adjacent to the outside may uniformly maintain the area located atthe outside based on the battery case 200, and the area in which the gasin the battery case 200 introduced into the dented portion 450 may bedischarged to the outside may also be maintained uniformly. Accordingly,there is an advantage that the gas exhaust effect by the dented portion450 may also be maintained.

Referring to FIGS. 4 to 6 , the lead film 400 may include a first leadfilm and a second lead film, the first lead film may be located at anupper portion of the electrode lead 300, and the second lead film may belocated at a lower portion of the electrode lead 300. At this time, theelectrode lead 300 may be heat-fused together with the sealing portion250 in a state of being located between the first lead film and thesecond lead film, so that the first lead film and the second lead filmmay be connected to each other.

Accordingly, the lead film 400 may prevent the side surface of theelectrode lead 300 from being exposed to the outside, while improvingthe sealing properties of the sealing portion 250 and the electrode lead300.

For example, in the lead film 400, the dented portion 450 may be locatedin at least one of the first lead film and the second lead film. Morespecifically, in the lead film 400, the dented portion 450 may be formedin the first lead film or the second lead film based on the electrodelead 300, or the dented portion 450 may be formed on both the first leadfilm and the second lead film based on the electrode lead 300. However,the number of the dented portion 450 is not limited to the above, andthe lead film 400 may be formed in an appropriate number.

Accordingly, by adjusting the number of the dented portions 450 formedin the lead film 400, the durability and airtightness of the lead film400 may be controlled. In addition, by minimizing the number of thedented portion 450 as necessary, it is possible to simplify themanufacturing process and reduce the cost.

As an example, the dented portion 450 may be partially expanded towardthe upper and lower sides as compared with FIG. 7 by the gas inside thebattery cell 100. However, in this embodiment, since the dented portion450 is closed from the inside and outside of the battery case, thedegree of expansion may be relatively small, and the deformation of thecomponents may also be small accordingly.

A battery module according to another embodiment of the presentdisclosure includes the battery cell described above. Meanwhile, one ormore battery modules according to this embodiment may be packaged in apack case to form a battery pack.

The battery module described above and the battery pack including thesame may be applied to various devices. These devices may betransportation means such as electric bicycles, electric vehicles,hybrid electric vehicles, and the like, but the present disclosure isnot limited thereto, and the present disclosure may be applied variousdevices that can use a battery module and a battery pack including thesame, which is also within the scope of the right of the presentdisclosure.

Although the preferred embodiment of the present disclosure has beendescribed in detail above, the scope of the right of the presentdisclosure is not limited thereto, and various modifications andimprovements made by those skilled in the art using the basic concept ofthe present disclosure defined in the appended claims also fall withinthe scope of the right of the present disclosure.

1. A battery cell, comprising: a battery case having an accommodationportion in which an electrode assembly is mounted, and a sealing portionat an outer periphery of the battery case, the sealing portion having aheat fusion sealed structure; an electrode lead electrically connectedto an electrode tab of the electrode assembly, the electrode leadprotruding out of the battery case through the sealing portion; and alead film extending within the sealing portion adjacent to at least oneof an upper portion or a lower portion of the electrode lead, whereinthe lead film has a dented portion formed at an inside thereof, thedented portion extending through the sealing portion, and the dentedportion has a closed shape and is enclosed inside of the lead film. 2.The battery cell according to claim 1, wherein the dented portiondefines inner surfaces within the lead film, the lead film furthercomprising an inner layer covering at least one part of the innersurfaces of the dented portion of the lead film.
 3. The battery cellaccording to claim 2, wherein a material of the inner layer has a firstmelting point that is higher than a second melting point of a materialof the lead film, and the material of the inner layer is configured tobe non-reactive with an electrolytic solution.
 4. The battery cellaccording to claim 1, wherein the lead film contains a polyolefin-basedmaterial.
 5. The battery cell according to claim 3, wherein the innerlayer contains at least one of polyolefin-based materials,fluorine-based materials, or porous ceramic-based materials.
 6. Thebattery cell according to claim 1, wherein the lead film has a length ina longitudinal direction of the sealing portion greater than a width ofthe electrode lead in the longitudinal direction.
 7. The battery cellaccording to claim 1, wherein the dented portion overlies the electrodelead.
 8. The battery cell according to claim 6, wherein the dentedportion is located between an outer end of the electrode lead at anoutside of the battery case and an inner end of the lead film at aninside of the battery case.
 9. The battery cell according to claim 1,wherein the lead film has a width in a lateral direction of the sealingportion perpendicular to a longitudinal direction of the sealing portiongreater than a width of the sealing portion and smaller than a length ofthe electrode lead in the lateral direction.
 10. The battery cellaccording to claim 9, wherein a first end of the dented portion islocated between a first end of the sealing portion and a first end ofthe lead film, and a second end of the dented portion is located betweena second end of the sealing portion and a second end of the lead film.12. The battery cell according to claim 10, wherein the dented portionincludes a pair of first dented portions and a pair of second dentedportions connected to each other, each first dented portion extending inthe lateral direction of the sealing portion, and each second dentedportion extending along the longitudinal direction of the sealingportion.
 13. The battery cell according to claim 1, wherein the leadfilm includes a first lead film portion and a second lead film portion,the first lead film portion is located adjacent to an upper surface ofthe electrode lead, and the second lead film portion is located adjacentto a lower surface of the electrode lead.
 14. The battery cell accordingto claim 13, wherein the electrode lead is located between the firstlead film and the second lead film, and the first lead film and thesecond lead film are connected to each other at opposite sides of theelectrode lead.
 15. The battery cell according to claim 14, wherein thedented portion extends within at least one of the first lead filmportion or the second lead film portion.
 16. The battery cell accordingto claim 1, wherein an outer end of the dented portion extends beyond anouter surface of the battery case and is farther from the electrodeassembly than an outer edge of the sealing portion.
 17. The battery cellaccording to claim 16, wherein an inner end of the dented portionextends beyond an inner surface of the battery case closer to theelectrode assembly than an inner edge of the sealing portion.
 19. Thebattery cell according to claim 16, wherein an outer area of the dentedportion that extends beyond the outer surface of the battery case isgreater than an inner area of the dented portion that extends beyond aninner surface of the battery case.
 22. The battery cell according toclaim 1, wherein the lead film has a gas permeability of 20 Barrer to 60Barrer at 60° C.
 23. The battery cell according to claim 1, wherein thelead film is configured to have a moisture penetration amount of 0.02 gto 0.2 g for 10 years at 25° C., 50% RH.
 24. A battery module,comprising the battery cell according to claim 1.